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• W2010563208 abstract "Similar to many ureas, N-carbamoylamino acids were shown to be hydrolyzed in aqueous solution through elimination mechanisms at close to neutral pH, the nucleophilic attack of water being a minor process. Two competing elimination mechanisms can take place involving either cyanate or isocyanate transient intermediates. Peptide formation was observed and attributed to the latter pathway through the intermediacy of amino acid N-carboxyanhydride (NCA). Eventually, cyanate and its precursors (including urea) unexpectedly behave as amino acid activating agents because of their ability in amino acid carbamoylation. Owing to its ability to generate a background prebiotic production of NCAs on the primitive Earth, this reaction is suggested to have contributed to the origin of life process." @default.
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• W2010563208 date "2006-05-17" @default.
• W2010563208 modified "2023-10-10" @default.
• W2010563208 title "The Peptide Formation Mediated by Cyanate Revisited. <i>N</i>-Carboxyanhydrides as Accessible Intermediates in the Decomposition of <i>N</i>-Carbamoylamino Acids" @default.
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• W2010563208 doi "https://doi.org/10.1021/ja061339+" @default.
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