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- W2010569689 abstract "Abstract We report the formation of polyacrylate (molten state polymers: T g < room temperature) monolayers attached onto silica surfaces using covalently bonded initiators for radical‐chain polymerisation. In a first reaction step, the initiator is self‐assembled on the surface. In a subsequent reaction, the initiator is activated and the polymer formed in situ at the surface of the substrate with high grafting density (‘grafting from’ procedure). Moreover, the use of a living free radical process permits the molecular weight and polydispersity of the polymer chains to be controlled, and thus the polymer monolayer thickness also. We have also made a preliminary qualitative characterisation by X‐ray spectroscopy (XPS) and Fourier transformed infrared (FTIR) measurements. © 2002 Society of Chemical Industry" @default.
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- W2010569689 title "Formation of polyacrylate brushes on silica surfaces" @default.
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