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- W2010573079 abstract "Abstract The LaMnO 3 and LaB 0.2 Mn 0.8 O 3 (B = Co, Ni, Fe) perovskite-type oxides were prepared by the conventional co-precipitation method and studied as catalysts for the oxidation of vinyl chloride emission in the temperature range of 50–350 °C. Their physicochemical properties were characterized by ICP-AES, N 2 adsorption, XRD, H 2 -TPR, O 2 -TPD and XPS. Catalytic performances were evaluated for the oxidation of 1000 ppm of VC in air at a GHSV of 15,000 h −1 . The substituted LaB 0.2 Mn 0.8 O 3 samples showed higher catalytic activity than pure LaMnO 3 . Characterization results revealed that the catalytic activity of the perovskite oxides was greatly related to the low-temperature reducibility of the B site and the amount of adsorbed oxygen species and vacancies on the surface. The surface adsorbed oxygen species played a key role in the catalytic reaction and oxygen vacancies promoted the oxygen mobility. A reaction mechanism of vinyl chloride oxidation over LaMnO 3 -based perovskite oxides was proposed." @default.
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- W2010573079 date "2013-01-01" @default.
- W2010573079 modified "2023-10-13" @default.
- W2010573079 title "Catalytic oxidation of vinyl chloride emission over LaMnO3 and LaB0.2Mn0.8O3 (B=Co, Ni, Fe) catalysts" @default.
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- W2010573079 doi "https://doi.org/10.1016/j.apcatb.2012.09.056" @default.
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