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- W2010594419 abstract "A series of solution-processable near-infrared (NIR) electrochromic aromatic polyamides with starburst triarylamine units in the backbone were prepared by the phosphorylation polyamidation from a newly synthesized diamine monomer, N,N-bis[4-(4-methoxyphenyl-4′-aminophenylamino)phenyl]-N′,N′-di(4-methoxyphenyl)-p-phenylenediamine, and two aromatic dicarboxylic acids. These polymers were highly soluble in many organic solvents and showed useful levels of thermal stability associated with high glass-transition temperatures and high char yields (higher than 66% at 800 °C in nitrogen). The polymer films showed reversible electrochemical oxidation and electrochromism with high contrast ratio both in the visible range and NIR region, which also exhibited high coloration efficiency (CE), low switching time, and relatively high stability for long-term electrochromic operation. At the first oxidation stage, the polyamide Ia thin film revealed high coloration efficiency in NIR (CE = 290 cm2/C) region with reversible electroactive stability (more than 10000 times within 0.6% loss relative to its initial injected charge). As the dication radical form of second oxidation stage, the polymer film still exhibited excellent electrochromic/electroactive stability (more than 10 000 cyclic switches) with enhanced CE of 339 cm2/C." @default.
- W2010594419 created "2016-06-24" @default.
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- W2010594419 date "2011-03-15" @default.
- W2010594419 modified "2023-10-14" @default.
- W2010594419 title "Novel Starburst Triarylamine-Containing Electroactive Aramids with Highly Stable Electrochromism in Near-Infrared and Visible Light Regions" @default.
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- W2010594419 doi "https://doi.org/10.1021/cm103552k" @default.
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