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- W2010599552 abstract "This contribution describes the light harvesting efficiencies of new heteroleptic complexes of the form [M(L)(L′)] where L = p-tolylsulfonyldithiocarbimate (p-CH3C6H4SO2NCS22−); M = Ni(II), L′ = 2,2′-bipyridine (bpy) (1) or 1,10-phenanthroline (phen) (2) or N,N,N′,N′-tetramethylethylenediamine (tmed) (3); M = Pd(II), L′ = bpy (4) or phen (5) or tmed (6); and M = Pt(II), L′ = bpy (7) or phen (8) or tmed (9). These have been characterized by elemental analysis, IR, 1H and 13C NMR and UV-visible spectroscopies, and 1, 4 and 6 by single crystal X-ray diffraction. UV-visible absorption, electrochemical behavior and structural features of the ligand aromatic sulfonyldithiocarbimate containing free sulfonyl oxygen atoms serving as a typical anchoring group on TiO2 semiconductor electrode of the nickel complexes enable them to act as potential photosensitizers for solar energy conversion. This study widens the scope for square planar heteroleptic complexes with a suitable combination of metal ions and ligands to be explored as photosensitizers." @default.
- W2010599552 created "2016-06-24" @default.
- W2010599552 creator A5002838025 @default.
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- W2010599552 creator A5037375411 @default.
- W2010599552 creator A5039178202 @default.
- W2010599552 creator A5087578328 @default.
- W2010599552 date "2014-01-01" @default.
- W2010599552 modified "2023-10-16" @default.
- W2010599552 title "Light harvesting properties of some new heteroleptic dithiocarbimate–diamine/diimine complexes of Ni, Pd and Pt studied as photosensitizer in dye-sensitized TiO<sub>2</sub>solar cells" @default.
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- W2010599552 doi "https://doi.org/10.1039/c3nj00507k" @default.
- W2010599552 hasPublicationYear "2014" @default.
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