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- W201062478 abstract "Static, short-term corrosion screening tests of metals in molten sodium poiyphosphate are carried out at 700 deg C. For a series of iron-nickel-chromium alloys, the initial corrosion rates are found to decrease with increasing nickel content of the alloy. The high molybdenum-content alloys (Hastelloys) and high chromium-content alloys (Inconeis) exhibit relatively low corrosion rates. Among the pure metals, platinum, gold, vanadium, molybdenum, and tungsten are inert within limits of detection ((0.02 mg cm/sup -2/ hr/sup -1/). Analyses of corrosion product films on metals indicate that metallic phosphides are formed. Pretreatment of metal samples with elemental phosphorus and subsequent corrosion testing of such samples result in a significant lowering of the observed corrosion rate, thus demonstrating the protective effect of self-healing phosphide films. A sodium sulfate-sodium polyphosphate melt (proposed lowviscosity reactor fuel matrix) reacts vigorously with ironnickel alloys and molybdenum. Platinum again is unattacked (<0.02 mg cm/sup -2/ hr/sup -1/). Observed corrosion products are elemental phosphorus and metallic phosphides. Those tests involving sulfate also show sulfur and sulfur dioxide as additional products. (auth)" @default.
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- W201062478 date "1961-08-15" @default.
- W201062478 modified "2023-09-24" @default.
- W201062478 title "MOLTEN PHOSPHATE REACTOR FUELS. II. CORROSION OF METALS IN MOLTEN SODIUM POLYPHOSPHATE" @default.
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