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• W2010624867 abstract "The oxidation of 5-hydroxyalkenes by hydrogen peroxide, when catalyzed by CH3ReO3 (MTO), leads to functionalized tetrahydrofurans. In these cases, no tetrahydropyran was formed. The results show that the first reaction between the substrate and a peroxorhenium species formed from, and in equilibrium with, MTO and peroxide, yields an epoxide. This intermediate was not detected, however, because cyclization occurred so rapidly. 6-Hydroxyalkenes were similarly but more slowly converted to tetrahydropyran alcohols. A 4-hydroxyalkene was epoxidized but not cyclized." @default.
• W2010624867 created "2016-06-24" @default.
• W2010624867 creator A5079315830 @default.
• W2010624867 creator A5084394443 @default.
• W2010624867 date "2000-03-01" @default.
• W2010624867 modified "2023-10-16" @default.
• W2010624867 title "Regioselective oxidative cyclization of hydroxyalkenes to tetrahydrofurans catalyzed by methyltrioxorhenium" @default.
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• W2010624867 doi "https://doi.org/10.1016/s1381-1169(99)00294-0" @default.
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