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- W2010628478 abstract "The theory of the successive phase transitions in NaCN and KCN is presented. The elastic and electric dipole moments of a CN - ion are treated in a unified way using the symmetry adapted orientational variables with E g , T 2 g and T 1 u symmetries. Taking into account of the electronic polarizability of CN - and K + ions, the ground state of the electric dipolar arrangement is examined. It is shown that the electronic polarizability of a K + ion α K plays an essential role and that the experimentally observed antiferroelectric arrangement has the lowest energy when α K >3.5 Å 3 . The successive phase transition and the temperature dependence of the order parameters are examined." @default.
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- W2010628478 date "1988-12-15" @default.
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- W2010628478 title "Theory of Elastic and Electric Dipolar Orderings in NaCN and KCN" @default.
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- W2010628478 doi "https://doi.org/10.1143/jpsj.57.4265" @default.
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