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- W2010641926 abstract "The reactions of perfluorinated 3-methylindene and 1-methyleneindan in HNO3− HF (A), HNO3−SbF5−HF (B) and NO2BF4−HF (C) have been investigated. Along with nitrofluorination products, compounds with oxygen functions were formed which are not the products of transformations of nitroderivatives under the same reaction conditions. Based on analysis of experimental data and the results of quantum-chemical (MNDO) calculations of substrates, their radical cations and polyfluorinated nitroindanyl cations, a scheme of the process has been suggested involving the classical electrophilic route and the route with participation of substrate radical cations. The latter are assumed to be formed together with NO2· from the intermediate nitroindanyl cations." @default.
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- W2010641926 date "1992-08-01" @default.
- W2010641926 modified "2023-09-23" @default.
- W2010641926 title "Interaction of perfluorinated 3-methylindene and 1-methyleneindan with nitrating reagents in anhydrous HF" @default.
- W2010641926 doi "https://doi.org/10.1016/s0022-1139(00)80764-2" @default.
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