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• W2010648664 abstract "Abstract Calix[4]arene‐derived bis(iminophosphoranes) have been synthesised and assessed in palladium‐catalysed cross‐couplings between phenylboronic acid and aryl bromides orchlorides. TOFs of up to 35100 mol(ArPh formed) mol(Pd) –1 h –1 were observed in the reaction with 4‐bromoanisole. The ligands showed higher activities than the parent calixarene–diphosphanes. Their relatively good performances possibly arise from their ability to generate chelated intermediates in highly crowded metal environments, which incidentally facilitates the reductive elimination step." @default.
• W2010648664 created "2016-06-24" @default.
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• W2010648664 date "2012-03-28" @default.
• W2010648664 modified "2023-10-17" @default.
• W2010648664 title "Synthesis of Calixarene-Based Bis(iminophosphoranes) and Their Use in Suzuki-Miyaura Cross-Coupling" @default.
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• W2010648664 doi "https://doi.org/10.1002/ejoc.201200082" @default.
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