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- W2010649528 abstract "The thermodynamic equilibrium constants for the reduction of oxygen and sulphur functional groups in hydrogen and in tetralin were calculated for the temperature range 327–527 °C. All the reduction reactions of the oxygen groups are thermodynamically favourable both with hydrogen and with tetralin. The reduction reactions of all the sulphur functional groups in tetralin are favourable except for the reductions of thiophenes below 407 °C. However, molecular hydrogen cannot reduce thiophenes or aryl sulphides below about 590 °C. Reactions in which oxygen from water is captured by the organic matrix are not favourable reactions; however, capturing of sulphur from hydrogen sulphide or alkyl thiols can occur in this range of temperatures. The most stable products are condensed thiophenic structures." @default.
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- W2010649528 date "1979-09-01" @default.
- W2010649528 modified "2023-09-27" @default.
- W2010649528 title "Thermodynamics of the transformations of oxygen- and sulphur-containing functional groups during coal liquefaction in hydrogen and hydrogen donor" @default.
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- W2010649528 doi "https://doi.org/10.1016/0016-2361(79)90219-9" @default.
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