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- W2010652880 abstract "The cothermolysis of acetyl-, pivaloyl-, adamantoyl-, benzoyl-, and mesitoyltris(trimethylsilyl)silane (1−5) with acetone and benzophenone at 140 °C was investigated. The reaction of the silene formed from 1 with acetone and benzophenone afforded no adducts but produced a dimer of the silene. The silene produced thermally from 2 reacted with acetone to give two cyclopropane derivatives (11) and (12), and a silyl enol ether (9). Similar reaction of the silene formed from 3 with acetone afforded a cyclopropane derivative (14), along with a silyl enol ether (13). The reaction of the silene generated from 4 with acetone gave bicyclic compound 16 as the sole product, while similar reaction of the silene formed from 5 produced 2,2-dimethylmesityl(trimethylsiloxy)ethene. The thermolysis of 2 and 3 with benzophenone yielded the respective cycloheptatrienes 20 and 22, and silyl enol ethers 19 and 21, respectively. Similarly, the reactions of the silenes produced from 4 and 5 afforded silyl enol ethers 26 and 28. Compound 22 was characterized by X-ray crystallography." @default.
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- W2010652880 title "Silicon−Carbon Unsaturated Compounds. 58. Reactions of Silenes Produced Thermally from Acylpolysilanes with Carbonyl Compounds" @default.
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- W2010652880 doi "https://doi.org/10.1021/om960204h" @default.
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