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- W2010671434 abstract "Fluorescence quenching has been observed in 10−4 to 10−7M solutions of metal-free phthalocyanine in 1-chloronaphthalene at 77°K. This quenching is attributed to singlet–triplet fusion. A triplet lifetime of 200 μsec was measured at 77°K. A dipole–dipole interaction formulation for singlet excitation migration was adapted to the singlet–triplet fusion process. A critical distance of about 200 Å was computed for the system under study. Unlike in singlet excitation migration, this critical distance depends on the experimental illumination conditions. If singlet–triplet fusion plays a role in photogeneration of charge carriers in metal-free phthalocyanine thin films, a photocurrent linear in light intensity, in the absence of recombination and trapping effects, can be understood." @default.
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- W2010671434 title "Singlet–triplet fusion in metal‐free phthalocyanine" @default.
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- W2010671434 doi "https://doi.org/10.1063/1.433612" @default.
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