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- W2010676586 abstract "(Triphenylphosphine)phenylselenolatogold(I), Ph3PAuSePh (1), and the corresponding dppm derivative, [(dppm)(AuSePh)2] (3), are prepared from Me3SiSePh and the appropriate (phosphine)chlorogold(I) complex. The reaction between Ph3PAuCl, Ph2Se2 and AgSbF6 leads to the salt [(Ph3PAu)2SePh]+SbF−6 (2), with a bridging PhSe ligand. X-ray structure analyses of 1 and 2 confirm the expected linear geometry at gold and reveal short Au-Au contacts; both compounds may thus be regarded as loose dimers." @default.
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- W2010676586 date "1990-10-01" @default.
- W2010676586 modified "2023-10-14" @default.
- W2010676586 title "Gold complexes with selenium ligands, I. Preparation and crystal structures of phenylselenolato‐gold(I) complexes" @default.
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- W2010676586 doi "https://doi.org/10.1002/cber.19901231008" @default.
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