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- W2010679546 abstract "Salts of one series of [Co en2L Cl]2+ cations have been prepared, where en represents bidenate ethylenediamine and L is a diamine acting as a unidentate ligand. They are tentatively assigned a cis-configuration on the basis of their visible spectra. The base strength of the diamines are decreased by factors of 103–107 when the other NH2 end is coordinated to cobalt(III), and in 0·1 mol dm−3 acid, the complexes exist as the corresponding protonated forms [Co en2(LH)Cl]3+. The rate constants for both spontaneous and mercury(II)-induced aquations of these trivalent cations have been determined over a range of temperatures and the activation parameters calculated. The results are compared with data obtained for the divalent cis-chloro-n-butylaminebis(ethylendiamine)cobalt(III) cation with a view to investigate the effect of substrate charge on reactivities." @default.
- W2010679546 created "2016-06-24" @default.
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- W2010679546 date "1973-04-01" @default.
- W2010679546 modified "2023-09-26" @default.
- W2010679546 title "Octahedral cobalt(III) complexes of the chloropentammine type-XXIX Effect of substrate charge on reactivities of chloro(amine)bis(ethylenediamine)cobalt(III) cations" @default.
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- W2010679546 doi "https://doi.org/10.1016/0022-1902(73)80197-6" @default.
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