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- W2010684368 abstract "Abstract Solid solutions of cadmium and lead fluoroapatite [Pb (10− x ) Cd x (PO 4 ) 6 F 2 (0⩽ x ⩽5)] were synthesized by a wet process in a basic medium. Replacement of lead by cadmium induces a linear variation of the crystallographic parameters “ a ” and “ c ” according to Vegard's law. The cadmium content, as obtained from the refinement, is in agreement with the chemical analysis. The distribution of the lead and cadmium ions between two non-equivalent crystallographic sites, M(1) and M(2), was determined by the Rietveld method. The site-occupancy factors of atoms clearly indicate a preference of cadmium for site M(1) in the apatite structure in agreement with its smaller ionic radii. A progressive shift of the F − ion toward the center of the triangles formed by the site M(2) metals has been observed with increasing cadmium content." @default.
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- W2010684368 date "2007-02-01" @default.
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- W2010684368 title "Structure refinements of cadmium substituted lead fluoroapatites by powder X-ray pattern fitting" @default.
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- W2010684368 doi "https://doi.org/10.1016/j.jpcs.2006.10.012" @default.
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