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- W2010692904 abstract "The present investigation reports on the significant differences observed in the efficiency of the polymerization depending on the odd- or even-numbered methylene chains of diacetylenecarboxylates, CH3(CH2)m-1C⋮C−C⋮C(CH2)n-1CO2- (mono-[m,n]), incorporated in layered double hydroxide (LDH) clay. Upon γ-ray irradiation of the diacetylenecarboxylates, or mono-[m,n], in LDH clay, polymer hybrids or poly-[m,n]/LDH, which exhibited coloring from light orange to violet, were obtained. The color of the poly-[m,n]/LDH hybrids was strongly dependent on the extent of the polymerization degrees. Moreover, the polymerization degrees were controlled by the number of methylene spacers n between the carboxyl and diacetylene groups. An odd-numbered n for the methylene chain of mono-[m,n] was found to be the determining factor in the efficient polymerization of these self-assembling aggregates within the interlayers of LDH clay." @default.
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- W2010692904 date "2005-03-17" @default.
- W2010692904 modified "2023-10-03" @default.
- W2010692904 title "Odd−Even Effect of the Methylene Chain Number in the Template Polymerization of α,β-Diacetylenecarboxylates Incorporated in Layered Double Hydroxide Clay" @default.
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- W2010692904 doi "https://doi.org/10.1021/la047052c" @default.
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