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• W2010698413 abstract "Abstract The extraction of copper(II), nickel(II) and cobalt(II) from the aqueous phase with N,N'‐bis(salicylaldehydene)‐1,4‐bis‐( m ‐aminophenoxy)butane (MAS), which was synthesized from 1,4‐bis( m ‐aminophenoxy)butane and salicylaldehyde, was studied. Microanalytical data, elemental analysis, UV‐visible 1 H and 13 C n.m.r. spectra and IR‐spectra were used to confirm the structures. The extractability and selectivity of divalent cations were evaluated as a function of relationship between distribution ratio of the metal and pH or ligand concentration. Cu +2 showed the highest extractability and selectivity at pH 6.0, whereas Ni +2 and Co +2 showed at pH 9.2. The stoichiometries of the compounds formed were estimated to be CuL, CoL, NiL, where L is N,N'‐bis(salicylaldehydene)‐1,4‐bis‐( m ‐aminophenoxy)butane. It was concluded that MAS can effectively be used in solvent extraction of copper(II), nickel(II) and cobalt(II) from the aqeous phase to the organic phase." @default.
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• W2010698413 date "2007-04-01" @default.
• W2010698413 modified "2023-09-24" @default.
• W2010698413 title "Synthesis, Characterization and Structure Effects on Extractability and Selectivity of N,N'-Bis(Salicylaldehydene) - 1,4-Bis-(m-Aminophenoxy)Butane towards some Divalent Cations" @default.
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• W2010698413 doi "https://doi.org/10.1002/adic.200790014" @default.
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