Matches in SemOpenAlex for { <https://semopenalex.org/work/W2010723693> ?p ?o ?g. }
Showing items 1 to 94 of
94
with 100 items per page.
- W2010723693 endingPage "1888" @default.
- W2010723693 startingPage "1884" @default.
- W2010723693 abstract "The cationic tetranuclear cobalt complex of the geometry Cl-CoL-Cl-CoL-Cl-CoL-Cl-CoL (where L is 6,6′′′-dimethyl-2,2′:6′,2′′:6′′,2′′′-quaterpyridine) has been synthesized and structurally characterized. The structural unit contains one cationic ligand, two Eu(NO3)5 dianions, two solvent acetonitrile molecules and some disordered water molecules. The salt crystallizes in the monoclinic space group C2/c with a = 17.405 (3) Å, b = 28.700 (5) Å and c = 23.350 (5) Å, β = 95.14 (2)º. The cation is C 2 -symmetrical, the central Cl atom lies on the twofold axis. This structure is another example of centro-noncentro ambiguity: in the centrosymmetric model, the terminal Cl in the cation is disordered between the two ends of the chain. The Eu ion is coordinated by five nitro groups, the coordination number is 10–two oxygen atoms of every nitro group are involved in the coordination with the mean Eu–O distance of 2.52(3) Å. The quaterpyridine ligands are folded, the dihedral angle between the terminal ring planes is 29.3 (2) and 32.8 (3)º in the two symmetry independent ligands. In the crystal structure the coulombic attraction between the cations and anions seems to be a driving force; the ionic species make a chessboard-like pattern, the voids in such created structure are filled with the solvent-acetonitrile molecules as well as by some disordered waters. The C 2 -symmetrical cationic complex assumes the unprecedented linear geometry of the form Cl-CoL-Cl-CoL-Cl-CoL-Cl-CoL (where L is tetradentate 6,6′′′-dimethyl-2,2′:6′,2′′:6′′,2′′′-quaterpyridine)." @default.
- W2010723693 created "2016-06-24" @default.
- W2010723693 creator A5015642350 @default.
- W2010723693 creator A5042340251 @default.
- W2010723693 creator A5042973167 @default.
- W2010723693 date "2011-10-08" @default.
- W2010723693 modified "2023-09-26" @default.
- W2010723693 title "Unprecedented Architecture of the Linear (μ-Cl)-Tetranuclear Cobalt Complex with Quaterpyridine Ligand" @default.
- W2010723693 cites W1969623130 @default.
- W2010723693 cites W1979368277 @default.
- W2010723693 cites W1985303426 @default.
- W2010723693 cites W1988814033 @default.
- W2010723693 cites W1989773284 @default.
- W2010723693 cites W2043655315 @default.
- W2010723693 cites W2049294439 @default.
- W2010723693 cites W2058582355 @default.
- W2010723693 cites W2063448712 @default.
- W2010723693 cites W2080182825 @default.
- W2010723693 cites W2094012366 @default.
- W2010723693 cites W2096244632 @default.
- W2010723693 cites W2122956408 @default.
- W2010723693 cites W2131350133 @default.
- W2010723693 cites W2151158020 @default.
- W2010723693 cites W4252164638 @default.
- W2010723693 doi "https://doi.org/10.1007/s10870-011-0195-3" @default.
- W2010723693 hasPublicationYear "2011" @default.
- W2010723693 type Work @default.
- W2010723693 sameAs 2010723693 @default.
- W2010723693 citedByCount "6" @default.
- W2010723693 countsByYear W20107236932013 @default.
- W2010723693 countsByYear W20107236932014 @default.
- W2010723693 countsByYear W20107236932016 @default.
- W2010723693 crossrefType "journal-article" @default.
- W2010723693 hasAuthorship W2010723693A5015642350 @default.
- W2010723693 hasAuthorship W2010723693A5042340251 @default.
- W2010723693 hasAuthorship W2010723693A5042973167 @default.
- W2010723693 hasBestOaLocation W20107236931 @default.
- W2010723693 hasConcept C112887158 @default.
- W2010723693 hasConcept C115624301 @default.
- W2010723693 hasConcept C116569031 @default.
- W2010723693 hasConcept C170493617 @default.
- W2010723693 hasConcept C178790620 @default.
- W2010723693 hasConcept C179104552 @default.
- W2010723693 hasConcept C183882617 @default.
- W2010723693 hasConcept C185592680 @default.
- W2010723693 hasConcept C2777463227 @default.
- W2010723693 hasConcept C32909587 @default.
- W2010723693 hasConcept C43617362 @default.
- W2010723693 hasConcept C514695523 @default.
- W2010723693 hasConcept C515602321 @default.
- W2010723693 hasConcept C55493867 @default.
- W2010723693 hasConcept C61276311 @default.
- W2010723693 hasConcept C71240020 @default.
- W2010723693 hasConcept C8010536 @default.
- W2010723693 hasConcept C89025888 @default.
- W2010723693 hasConceptScore W2010723693C112887158 @default.
- W2010723693 hasConceptScore W2010723693C115624301 @default.
- W2010723693 hasConceptScore W2010723693C116569031 @default.
- W2010723693 hasConceptScore W2010723693C170493617 @default.
- W2010723693 hasConceptScore W2010723693C178790620 @default.
- W2010723693 hasConceptScore W2010723693C179104552 @default.
- W2010723693 hasConceptScore W2010723693C183882617 @default.
- W2010723693 hasConceptScore W2010723693C185592680 @default.
- W2010723693 hasConceptScore W2010723693C2777463227 @default.
- W2010723693 hasConceptScore W2010723693C32909587 @default.
- W2010723693 hasConceptScore W2010723693C43617362 @default.
- W2010723693 hasConceptScore W2010723693C514695523 @default.
- W2010723693 hasConceptScore W2010723693C515602321 @default.
- W2010723693 hasConceptScore W2010723693C55493867 @default.
- W2010723693 hasConceptScore W2010723693C61276311 @default.
- W2010723693 hasConceptScore W2010723693C71240020 @default.
- W2010723693 hasConceptScore W2010723693C8010536 @default.
- W2010723693 hasConceptScore W2010723693C89025888 @default.
- W2010723693 hasIssue "12" @default.
- W2010723693 hasLocation W20107236931 @default.
- W2010723693 hasOpenAccess W2010723693 @default.
- W2010723693 hasPrimaryLocation W20107236931 @default.
- W2010723693 hasRelatedWork W146351320 @default.
- W2010723693 hasRelatedWork W15120608 @default.
- W2010723693 hasRelatedWork W2027234461 @default.
- W2010723693 hasRelatedWork W2031538813 @default.
- W2010723693 hasRelatedWork W2088672700 @default.
- W2010723693 hasRelatedWork W2091408581 @default.
- W2010723693 hasRelatedWork W2094957800 @default.
- W2010723693 hasRelatedWork W2463657710 @default.
- W2010723693 hasRelatedWork W2902603126 @default.
- W2010723693 hasRelatedWork W646380683 @default.
- W2010723693 hasVolume "41" @default.
- W2010723693 isParatext "false" @default.
- W2010723693 isRetracted "false" @default.
- W2010723693 magId "2010723693" @default.
- W2010723693 workType "article" @default.