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• W2010734640 abstract "The peculiar characteristics of the ligand neocuproine (2,9-dimethylphenanthroline) allow a number of exchange equilibrium studies between the low valence complex [Pd(η 2 -nq)(Neocup)] (nq = naphthoquinone; Neocup = neocuproine) and several alkenes and alkynes. A new order of stability which compares differently unsaturated molecules was established. An overview of the factors governing the stability of palladium(0) alkene and alkyne derivatives as a function of the steric and electronic characteristics of both the unsaturated molecule and the ligand becomes accessible and a comparison with the previously determined order was therefore feasible. Such a comparison enlightens the importance of the substituent methyl groups in ortho position of the hetero-aromatic ring which represents the molecular fragment common to all the ligands considered. Taking advantage of the steric requirements of the alkene tmetc (tmetc = tetramethylethylenetetracarboxylate) a kinetic investigation of the reaction between the olefin itself and the complexes [Pd(η 2 -dmfu)(L-L′)] (dmfu = dimethylfumarate; L–L′ = 8-diphenylphosphanyl-2-methyl-quinoline, neocuproine, phenanthroline) was carried out. The structures of the complexes [Pd(η 2 -dmfu)(DPPQ)] and [Pd(η 2 -deta)(Neocup)] (deta = but-2-ynedioc acid diethyl ester) were also reported in the present paper. The structure of the latter represents the first example of a palladium(0) complex in which the N 2 C 2 donor set around the metal centre is supported by a chelating η 2 -alkyne." @default.
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• W2010734640 date "2009-02-01" @default.
• W2010734640 modified "2023-09-23" @default.
• W2010734640 title "The role of ancillary ligands and of electron poor alkenes and alkynes in stabilizing Pd(0) derivatives: A comparative study" @default.
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• W2010734640 doi "https://doi.org/10.1016/j.jorganchem.2008.11.012" @default.
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