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- W2010743137 abstract "Silver-coloured brittle single crystals of the hitherto unknown compound Rb3Au7 were synthesized by the reaction of RbN3 and gold powder at 500 °C. The structure was determined from X-ray single-crystal diffractometer data: space group Cmmm, Z=2, a=5.585(2) Å, b=13.252(2) Å, c=7.258(1) Å, R/Rw (w=1)=0.046/0.057, N(Fo2)⩾3o(Fo2)=405 and N(var.)=22. The structure consists of a three-dimensional gold framework. Rubidium atoms occupy channel-like cavities within the gold partial structure. Silberfarbene, spröde Einkristalle eines bislang unbekannten Rb3Au7 wurden durch Umsetzung von RbN3 und Goldpulver bei 500 °C hergestellt. Die Struktur wurde aus Röntgen-Einkristall-Diffraktometerdaten bestimmt: Raumgruppe Cmmm, Z=2, a=5,585(2) Å, b=13,252(2) Å, c=7,258(1) Å, R/Rw (w=1)=0,046/0,057, Z(F02)⩾3o(Fo2)=405 and Z(Var.)=22. Die Struktur besteht aus einem dreidimensionalen Goldgerüst. Die Rubidiumatome besetzen kanalartige Hohlräume innerhalb der Gold-Teilstruktur." @default.
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- W2010743137 date "1993-09-01" @default.
- W2010743137 modified "2023-10-09" @default.
- W2010743137 title "Eine neue verbindung im system rubidium-gold: synthese und struktur von Rb3Au7" @default.
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- W2010743137 doi "https://doi.org/10.1016/0925-8388(93)90435-p" @default.
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