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- W2010746610 abstract "Rhodium has been introduced to protonated zeolite Y (HY) and partially protonated zeolite Y (5% HNaY) as the tris-allyl complex, Rh(C3H5)3. The resulting zeolite, RhHY or RhNaY, may be reduced in CO to yield Rh(CO)2+ or Rh6(CO)16 depending on the reaction conditions. Reaction with phosphines suggests that rhodium lies both within the zeolite framework and on the zeolite surface. When the zeolite supported phosphine complexes are used as solution hydroformylation catalysts, all of the observed activity appears to come from the solution phase as rhodium is leached from the support." @default.
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- W2010746610 date "1987-04-01" @default.
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- W2010746610 title "Zeolite supported rhodium carbonyls from Rh(allyl)3 and their use as 1-hexene hydroformylation catalysts" @default.
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- W2010746610 doi "https://doi.org/10.1016/s0020-1693(00)84695-2" @default.
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