FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2010754920> ?p ?o ?g. }

• W2010754920 endingPage "68" @default.
• W2010754920 startingPage "61" @default.
• W2010754920 abstract "Transmetallation of Li[A′] (A′ = [1,3-(SiMe3)2C3H3]−) with sodium tert-butoxide produces the corresponding sodium salt, which crystallizes from THF/toluene in the form of a cyclic tetramer, {Na[A′](thf)}4. The Na atoms are in a square planar arrangement, bridged with π-bound allyl ligands; the Na–C distances range from 2.591(3)–2.896(3) Å, with an average of 2.70 Å. The geometries of several model organosodium complexes containing cyclopentadienyl and allyl ligands were optimized with density functional theory methods. The optimized structures were used with the gauge-including atomic orbital (GIAO) method to calculate their 23Na NMR magnetic shielding values. Unlike the case with NaCp, the chemical shift of unsubstituted Na(C3H5) is very sensitive to the presence of coordinated THF (causing a 20 ppm upfield shift); silyl substitution has an even larger effect (30 ppm upfield shift). The observed 23Na shift of δ −3.3 ppm for Na[A′] in THF-d8, however, cannot be reliably distinguished from that calculated for the [Na(thf)4]+ cation alone." @default.
• W2010754920 created "2016-06-24" @default.
• W2010754920 creator A5023541100 @default.
• W2010754920 creator A5049913526 @default.
• W2010754920 creator A5057803757 @default.
• W2010754920 creator A5091291778 @default.
• W2010754920 date "2010-12-01" @default.
• W2010754920 modified "2023-10-03" @default.
• W2010754920 title "A tetrameric allyl complex of sodium, and computational modeling of the 23Na–allyl chemical shift" @default.
• W2010754920 cites W1780646024 @default.
• W2010754920 cites W1963532581 @default.
• W2010754920 cites W1967814169 @default.
• W2010754920 cites W1972968905 @default.
• W2010754920 cites W1973837481 @default.
• W2010754920 cites W1981368803 @default.
• W2010754920 cites W1983601723 @default.
• W2010754920 cites W1984547239 @default.
• W2010754920 cites W1985529515 @default.
• W2010754920 cites W1985837948 @default.
• W2010754920 cites W1986967749 @default.
• W2010754920 cites W1989390095 @default.
• W2010754920 cites W1989779406 @default.
• W2010754920 cites W1992389466 @default.
• W2010754920 cites W1995334952 @default.
• W2010754920 cites W1998149179 @default.
• W2010754920 cites W1998467758 @default.
• W2010754920 cites W1998554892 @default.
• W2010754920 cites W2002779312 @default.
• W2010754920 cites W2002795496 @default.
• W2010754920 cites W2002918439 @default.
• W2010754920 cites W2004697038 @default.
• W2010754920 cites W2005416136 @default.
• W2010754920 cites W2008113600 @default.
• W2010754920 cites W2008778253 @default.
• W2010754920 cites W2012776495 @default.
• W2010754920 cites W2013200312 @default.
• W2010754920 cites W2015983668 @default.
• W2010754920 cites W2016662066 @default.
• W2010754920 cites W2021388898 @default.
• W2010754920 cites W2026442291 @default.
• W2010754920 cites W2028362202 @default.
• W2010754920 cites W2031764960 @default.
• W2010754920 cites W2033734487 @default.
• W2010754920 cites W2034397756 @default.
• W2010754920 cites W2035247052 @default.
• W2010754920 cites W2035365931 @default.
• W2010754920 cites W2035477102 @default.
• W2010754920 cites W2039444960 @default.
• W2010754920 cites W2041978832 @default.
• W2010754920 cites W2043898882 @default.
• W2010754920 cites W2047602180 @default.
• W2010754920 cites W2050652551 @default.
• W2010754920 cites W2052442881 @default.
• W2010754920 cites W2055053360 @default.
• W2010754920 cites W2057738674 @default.
• W2010754920 cites W2064998085 @default.
• W2010754920 cites W2067290420 @default.
• W2010754920 cites W2073027046 @default.
• W2010754920 cites W2079727389 @default.
• W2010754920 cites W2082412789 @default.
• W2010754920 cites W2084427563 @default.
• W2010754920 cites W2085374177 @default.
• W2010754920 cites W2090101451 @default.
• W2010754920 cites W2094797484 @default.
• W2010754920 cites W2105816906 @default.
• W2010754920 cites W2121519228 @default.
• W2010754920 cites W2143378751 @default.
• W2010754920 cites W2167070649 @default.
• W2010754920 cites W2167348185 @default.
• W2010754920 cites W2168715007 @default.
• W2010754920 cites W2402743136 @default.
• W2010754920 cites W2952281525 @default.
• W2010754920 cites W2952914620 @default.
• W2010754920 cites W4239757447 @default.
• W2010754920 doi "https://doi.org/10.1016/j.ica.2010.07.079" @default.
• W2010754920 hasPublicationYear "2010" @default.
• W2010754920 type Work @default.
• W2010754920 sameAs 2010754920 @default.
• W2010754920 citedByCount "12" @default.
• W2010754920 countsByYear W20107549202012 @default.
• W2010754920 countsByYear W20107549202013 @default.
• W2010754920 countsByYear W20107549202015 @default.
• W2010754920 countsByYear W20107549202019 @default.
• W2010754920 countsByYear W20107549202020 @default.
• W2010754920 countsByYear W20107549202021 @default.
• W2010754920 countsByYear W20107549202022 @default.
• W2010754920 countsByYear W20107549202023 @default.
• W2010754920 crossrefType "journal-article" @default.
• W2010754920 hasAuthorship W2010754920A5023541100 @default.
• W2010754920 hasAuthorship W2010754920A5049913526 @default.
• W2010754920 hasAuthorship W2010754920A5057803757 @default.
• W2010754920 hasAuthorship W2010754920A5091291778 @default.
• W2010754920 hasConcept C142653250 @default.
• W2010754920 hasConcept C147597530 @default.
• W2010754920 hasConcept C152365726 @default.
• W2010754920 hasConcept C155647269 @default.
• W2010754920 hasConcept C161790260 @default.
• W2010754920 hasConcept C178790620 @default.

• next