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- W2010755055 endingPage "423" @default.
- W2010755055 startingPage "414" @default.
- W2010755055 abstract "The preparation and resolution of the titled conformationally stable biphenyl 1 has been performed in high chemical yield starting from creosol 2. Enantiopure biphenyls (aR)-(+)-1 and (aS)-(−)-1 were obtained by the corresponding menthylcarbonate diastereomer and successive reduction. The absolute configuration and specific rotation were correlated by X-ray analysis of the crystal structure of diastereopure menthylcarbonate (aS,1R,1′R,2S,2′S,5R,5′R)-(+)-16. Preliminary biological evaluation of both racemic enantiomers of 1 has been carried out on melanoma cell lines and significant and selective anticancer activity has been observed for the enantiomer (aS)-(−)-1." @default.
- W2010755055 created "2016-06-24" @default.
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- W2010755055 creator A5084131565 @default.
- W2010755055 date "2007-02-01" @default.
- W2010755055 modified "2023-10-05" @default.
- W2010755055 title "2,2′-Dihydroxy-3,3′-dimethoxy-5,5′-dimethyl-6,6′-dibromo-1,1′-biphenyl: preparation, resolution, structure and biological activity" @default.
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