FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2010777100> ?p ?o ?g. }

• W2010777100 endingPage "429" @default.
• W2010777100 startingPage "422" @default.
• W2010777100 abstract "2-Phenylaniline reacted with Pd(OAc)2 in toluene at room temperature for 24 h in a one-to-one molar ratio and with the system PdCl2, NaCl and NaOAc in a 1 (2-phenylaniline):1 (PdCl2):2 (NaCl):1 (NaOAc) molar ratio in methanol at room temperature for one week to give the dinuclear cyclopalladated compounds (μ-X)2[Pd{κ2-N2′,C1-2-(2′-NH2C6H4)C6H4}]2 [1a (X = OAc) and 1b (X = Cl)] in high yield. Moreover, the reaction between 2-phenylaniline and Pd(OAc)2 in one-to-one molar ratio in acid acetic at 60 °C for 4 h, followed by a metathesis reaction with LiBr, allowed isolation of the dinuclear cyclopalladated compound (μ-Br)2[Pd{κ2-N2′,C1-2-(2′-NH2C6H4)C6H4}]2 (1c) in moderate yield. A parallel treatment, but using monodeuterated acetic acid (DOAc) as solvent in the cyclopalladation reaction, allowed isolation of a mixture of compounds 1c, 1cd1 [Pd{κ2-N2′,C1-2-(2′-NH2C6H4)C6H4](μ-Br)2[Pd{κ2-N2′,C1-2-(2′-NH2C6H4)-3-d-C6H3] and 1cd2 (μ-Br)2[Pd{κ2-N2′,C1-2-(2′-NH2C6H4)-3-d-C6H3}]2 in moderate yield and with a deuterium content of ca. 60%. 1a and 1b reacted with pyridine and PPh3 affording the mononuclear cyclopalladated compounds [Pd{κ2-N2′,C1-2-(2′-NH2C6H4)C6H4}(X)(L)] [2a (X = OAc, L = py), 2b (X = Cl, L = py), 3a (X = OAc, L = PPh3) and 3b (X = Cl, L = PPh3)] in a yield from moderate to high. Furthermore, 1a reacted with Na(acac) · H2O to give the mononuclear cyclopalladated compound 4 [Pd{κ2-N2′,C1-2-(2′-NH2C6H4)C6H4}(acac)] in moderate yield. 1H NMR studies in CDCl3 solution of 2a, 2b, 3a, 3b and 4 showed that 2a and 3a presented an intramolecular hydrogen bond between the acetato ligand and the amino group, and were involved in a dynamic equilibrium with water present in the CDCl3 solvent; and that the enantiomeric molecules of 2b and 4 were in a fast exchange at room temperature, while they were in a slow exchange for 2a, 3a and 3b. The X-ray crystal structures of 3b and 4 were determined. 3b crystallized in the triclinic space group P1¯ with a = 9.9170(10), b = 10.4750(10), c = 12.0890(10) Å, α = 98.610(10)°, β = 94.034(10)° and γ = 99.000(10)° and 4 in the monoclinic space group P21/a with a = 11.5900(10), b = 11.2730(10), c = 12.2150(10) Å, α = 90°, β = 107.6560(10)° and γ = 90°." @default.
• W2010777100 created "2016-06-24" @default.
• W2010777100 creator A5012558097 @default.
• W2010777100 creator A5017506922 @default.
• W2010777100 creator A5020221698 @default.
• W2010777100 creator A5030477055 @default.
• W2010777100 creator A5061420118 @default.
• W2010777100 date "2005-01-01" @default.
• W2010777100 modified "2023-10-18" @default.
• W2010777100 title "The cyclopalladation reaction of 2-phenylaniline revisited" @default.
• W2010777100 cites W178547330 @default.
• W2010777100 cites W1966255413 @default.
• W2010777100 cites W1967257100 @default.
• W2010777100 cites W1968054514 @default.
• W2010777100 cites W1973469579 @default.
• W2010777100 cites W1977756947 @default.
• W2010777100 cites W1981579427 @default.
• W2010777100 cites W1990536808 @default.
• W2010777100 cites W1996398794 @default.
• W2010777100 cites W1996637371 @default.
• W2010777100 cites W2012284933 @default.
• W2010777100 cites W2017677712 @default.
• W2010777100 cites W2018923009 @default.
• W2010777100 cites W2033239130 @default.
• W2010777100 cites W2035409838 @default.
• W2010777100 cites W2042653815 @default.
• W2010777100 cites W2058571892 @default.
• W2010777100 cites W2062020264 @default.
• W2010777100 cites W2062477343 @default.
• W2010777100 cites W2070310556 @default.
• W2010777100 cites W2085539543 @default.
• W2010777100 cites W2128594801 @default.
• W2010777100 cites W2140268503 @default.
• W2010777100 cites W2951174106 @default.
• W2010777100 cites W2953149348 @default.
• W2010777100 doi "https://doi.org/10.1016/j.jorganchem.2004.07.067" @default.
• W2010777100 hasPublicationYear "2005" @default.
• W2010777100 type Work @default.
• W2010777100 sameAs 2010777100 @default.
• W2010777100 citedByCount "56" @default.
• W2010777100 countsByYear W20107771002012 @default.
• W2010777100 countsByYear W20107771002013 @default.
• W2010777100 countsByYear W20107771002014 @default.
• W2010777100 countsByYear W20107771002015 @default.
• W2010777100 countsByYear W20107771002016 @default.
• W2010777100 countsByYear W20107771002017 @default.
• W2010777100 countsByYear W20107771002018 @default.
• W2010777100 countsByYear W20107771002019 @default.
• W2010777100 countsByYear W20107771002020 @default.
• W2010777100 countsByYear W20107771002021 @default.
• W2010777100 countsByYear W20107771002022 @default.
• W2010777100 countsByYear W20107771002023 @default.
• W2010777100 crossrefType "journal-article" @default.
• W2010777100 hasAuthorship W2010777100A5012558097 @default.
• W2010777100 hasAuthorship W2010777100A5017506922 @default.
• W2010777100 hasAuthorship W2010777100A5020221698 @default.
• W2010777100 hasAuthorship W2010777100A5030477055 @default.
• W2010777100 hasAuthorship W2010777100A5061420118 @default.
• W2010777100 hasConcept C134121241 @default.
• W2010777100 hasConcept C13965031 @default.
• W2010777100 hasConcept C153914509 @default.
• W2010777100 hasConcept C155647269 @default.
• W2010777100 hasConcept C161790260 @default.
• W2010777100 hasConcept C178790620 @default.
• W2010777100 hasConcept C185592680 @default.
• W2010777100 hasConcept C191897082 @default.
• W2010777100 hasConcept C192562407 @default.
• W2010777100 hasConcept C2776673659 @default.
• W2010777100 hasConcept C2778142098 @default.
• W2010777100 hasConcept C2779485729 @default.
• W2010777100 hasConcept C2779607525 @default.
• W2010777100 hasConcept C2780471494 @default.
• W2010777100 hasConcept C2994067411 @default.
• W2010777100 hasConcept C44228677 @default.
• W2010777100 hasConcept C521977710 @default.
• W2010777100 hasConceptScore W2010777100C134121241 @default.
• W2010777100 hasConceptScore W2010777100C13965031 @default.
• W2010777100 hasConceptScore W2010777100C153914509 @default.
• W2010777100 hasConceptScore W2010777100C155647269 @default.
• W2010777100 hasConceptScore W2010777100C161790260 @default.
• W2010777100 hasConceptScore W2010777100C178790620 @default.
• W2010777100 hasConceptScore W2010777100C185592680 @default.
• W2010777100 hasConceptScore W2010777100C191897082 @default.
• W2010777100 hasConceptScore W2010777100C192562407 @default.
• W2010777100 hasConceptScore W2010777100C2776673659 @default.
• W2010777100 hasConceptScore W2010777100C2778142098 @default.
• W2010777100 hasConceptScore W2010777100C2779485729 @default.
• W2010777100 hasConceptScore W2010777100C2779607525 @default.
• W2010777100 hasConceptScore W2010777100C2780471494 @default.
• W2010777100 hasConceptScore W2010777100C2994067411 @default.
• W2010777100 hasConceptScore W2010777100C44228677 @default.
• W2010777100 hasConceptScore W2010777100C521977710 @default.
• W2010777100 hasIssue "2" @default.
• W2010777100 hasLocation W20107771001 @default.
• W2010777100 hasOpenAccess W2010777100 @default.
• W2010777100 hasPrimaryLocation W20107771001 @default.
• W2010777100 hasRelatedWork W2034808885 @default.
• W2010777100 hasRelatedWork W2081956061 @default.

• next