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• W2010837498 abstract "New phosphorus-bridged ligands incorporating both indenyl and carboranyl moieties were prepared. Reaction of iPr2NP(C9H7)Cl (1) with 1 equiv of Li2C2B10H10 gave, after treatment with 1 equiv of n-BuLi, the dilithium salt [iPr2NP(C9H6)(C2B10H10)]Li2(OEt2)1.5 (2). 2 can be conveniently converted into its neutral counterpart iPr2NP(C9H7)(C2B10H11) (4) by treatment with excess dry Me3NHCl in CH2Cl2. Mixing 2 and 4 in a 1:1 molar ratio afforded quantitatively the monolithium salt [iPr2NP(C9H6)(C2B10H11)]Li(DME)3 (3). Reaction of YbI2 with 1 equiv of 2 gave the organoytterbium(II) complex [η5:σ-iPr2NP(C9H6)(C2B10H10)]Yb(DME)2 (5). 5 reacted further with 1 equiv of 3 to afford the organoytterbium(III) complex [{η5:σ-iPr2NP(C9H6)(C2B10H10)}2Yb][Li(THF)3(Et2O)] (6). In sharp contrast, treatment of SmI2 with 1 equiv of 2 generated the trivalent organosamarium complex [{η5:σ-iPr2NP(C9H6)(C2B10H10)}2Sm][Li(DME)3] (7). Reaction of LnCl3 with 2 equiv of 2 gave the ionic complexes [{η5:σ-iPr2NP(C9H6)(C2B10H10)}2Ln][Li(L1)nL2]] (L1 = L2 = DME, n = 2, Ln = Sm (7), Nd (8), Er (9); L1 = DME, L2 = THF, n = 2, Ln = Y (10)). Reaction between equimolar amounts of LnCl3 and 2 resulted in the isolation of the lanthanocene chlorides [{[η5:σ-iPr2NP(C9H6)(C2B10H10)]LnCl}2(μ-Cl)3Li(DME)][Li(DME)3]2 (Ln = Er (11), Y (12)). The chloro groups in these complexes can be replaced by other moieties. For example, reaction of 12 with 2 equiv of KCH2Ph afforded the unexpected compound {[η5:σ-iPr2NP(C9H6)(C2B10H10)]2Y}{(η6-C6H5CH3)2K} (13) and treatment of 12 with 2 equiv of NaBH4 produced the organoyttrium hydrides [{η5:σ-iPr2NP(C9H6)(C2B10H10)}Y{(μ-H)3BH}2][Li(DME)3] (14). All complexes were fully characterized by various spectroscopic techniques and elemental analyses. The structures of some of the compounds were further confirmed by single-crystal X-ray analyses." @default.
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• W2010837498 date "2004-01-20" @default.
• W2010837498 modified "2023-10-12" @default.
• W2010837498 title "Synthesis, Structural Characterization, and Reactivity of Rare-Earth Complexes Derived from A New Phosphorus-Bridged Versatile Ligand, <i>ⁱ</i>Pr₂NP(C₉H₇)(C₂B₁₀H₁₁)" @default.
• W2010837498 cites W1969538509 @default.
• W2010837498 cites W1970435086 @default.
• W2010837498 cites W1971839381 @default.
• W2010837498 cites W1972194888 @default.
• W2010837498 cites W1972765162 @default.
• W2010837498 cites W1972855453 @default.
• W2010837498 cites W1974800750 @default.
• W2010837498 cites W1975050883 @default.
• W2010837498 cites W1976071630 @default.
• W2010837498 cites W1976147291 @default.
• W2010837498 cites W1986989675 @default.
• W2010837498 cites W1989344197 @default.
• W2010837498 cites W1991629018 @default.
• W2010837498 cites W1993833542 @default.
• W2010837498 cites W1995880600 @default.
• W2010837498 cites W1998894389 @default.
• W2010837498 cites W2004065812 @default.
• W2010837498 cites W2006395860 @default.
• W2010837498 cites W2006707261 @default.
• W2010837498 cites W2009106917 @default.
• W2010837498 cites W2010496555 @default.
• W2010837498 cites W2011025971 @default.
• W2010837498 cites W2013430937 @default.
• W2010837498 cites W2014536675 @default.
• W2010837498 cites W2015989455 @default.
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• W2010837498 cites W2027291680 @default.
• W2010837498 cites W2028802681 @default.
• W2010837498 cites W2033880477 @default.
• W2010837498 cites W2039789849 @default.
• W2010837498 cites W2041482802 @default.
• W2010837498 cites W2041550040 @default.
• W2010837498 cites W2049912607 @default.
• W2010837498 cites W2050862375 @default.
• W2010837498 cites W2051200722 @default.
• W2010837498 cites W2056352981 @default.
• W2010837498 cites W2058250623 @default.
• W2010837498 cites W2060615558 @default.
• W2010837498 cites W2081607503 @default.
• W2010837498 cites W2083831281 @default.
• W2010837498 cites W2084069784 @default.
• W2010837498 cites W2085980268 @default.
• W2010837498 cites W2087480509 @default.
• W2010837498 cites W2087537218 @default.
• W2010837498 cites W2093709987 @default.
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• W2010837498 cites W2149295256 @default.
• W2010837498 cites W2171540845 @default.
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• W2010837498 cites W2312626729 @default.
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• W2010837498 cites W3138775290 @default.
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• W2010837498 doi "https://doi.org/10.1021/om034268l" @default.
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