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- W2010911067 abstract "A macrocyclised phenyl cinnamate dimer with a chiral spacer was prepared, and its photochemistry was compared with that of a precursor linear dimer and corresponding monomeric compounds. Although ultraviolet irradiation of the monomer resulted merely in cis–trans isomerisation of a cinnamate, irradiation of the cyclic and linear dimers induced intra-molecular [2 + 2] photodimerisation of cinnamate groups. Photodimerisation in the cyclic dimer proceeded 20 times faster than in the linear dimer. In a nematic liquid crystal, the cyclic dimer exhibited a high helical twisting power of 27.5 μm−1, which decreased to 6.7 μm−1 with dimerisation. A macrocyclised dimer such as this can be used as a photoresponsive chiral dopant for nematic liquid crystals." @default.
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- W2010911067 date "2013-07-01" @default.
- W2010911067 modified "2023-09-27" @default.
- W2010911067 title "Macrocyclised pheynyl cinnamate dimer utilisable as photoresponsive chiral dopant for nematic liquid crystals" @default.
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- W2010911067 doi "https://doi.org/10.1080/02678292.2013.790094" @default.
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