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• W2010945640 abstract "In contrast to the rapid and chemically reversible two-electron ECE′ reductive elimination reaction[(C5Me5)ClM(bpy)]+ + 2e− → (C5Me5)M(bpy)+Cl−,M=Rh or Ir, the analogous cobalt system exhibits two separate one-electron steps (EC + E′ process) with a persistent, EPR-spectroscopically characterized cobalt(II) intermediate [(C5Me5)Co(bpy)]+. Within the series of coordinatively unsaturated homologous species (C5Me5)M(bpy), the cobalt derivative exhibits the smallest and the iridium homologue the largest metal(I)-to-bpy electron transfer in the ground state, as evident from electrochemical potentials and long-wavelength absorption data. A comparison within that homologous series indicates why the rhodium system, with its intermediate position, is most suitable for hydride transfer catalysis." @default.
• W2010945640 created "2016-06-24" @default.
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• W2010945640 date "1996-11-01" @default.
• W2010945640 modified "2023-10-16" @default.
• W2010945640 title "Electron transfer and chloride ligand dissociation in complexes [(C5Me5)ClM(bpy)]+/[(C5Me5)M(bpy)]n (M=Co, Rh, Ir;n = 2+, +, 0, −): A combined electrochemical and spectroscopic investigation" @default.
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• W2010945640 doi "https://doi.org/10.1016/s0022-328x(96)06426-1" @default.
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