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- W2010959936 abstract "The effects of partially replacing Cu by borate anions in the system YSr2−xBaxCu3−z(BO3)zOy (YSr2−xBaxCu3−zBzO7−δ) have been examined. The optimum substitution level to give single-phase samples was found to be z≈0.5. Borate-substituted samples of this composition were found to be non-superconducting as prepared, but superconductivity could be induced by the partial replacement of Y by Ca (for samples with 0.5≤×≤1.5), or by high oxygen pressure treatment (for 1.0≤×≤1.5). The highest Tc onset recorded for a single-phase sample was 55 K for Y0.85Ca0.15Ba1.5Cu2.5B0.5O7 annealed in high pressure oxygen. The unit cell symmetry changes from orthorhombic for the Ba-free phase (x=0)to tetragonal at higher Ba contents, which appears to be associated with a randomisation of the orientations of the borate groups." @default.
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- W2010959936 date "1993-09-01" @default.
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- W2010959936 title "BO3-3 substitutions in phases related to YBa2Cu3O7. superconducting properties of (Y, Ca) (Ba, Sr)2Cu3−z(BO3)zOy" @default.
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- W2010959936 doi "https://doi.org/10.1016/0921-4534(93)90380-9" @default.
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