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- W2010982989 abstract "Various mechanisms are constructed with the aid of information on associated reactions and tested in the light of the theory of two-variable oscillating reactions as well as by means of computer simulations. Reactions were run mainly at [HClO4]0= 0.035 to 0.080, [KIO3]0= 0.40, and [H2O2]0= 0.30 mol l.–1 and compared with computer results for a promising mechanism. Agreement is so good with respect to the induction period, the pulses of [I–] and the rate of O2 evolution, the abrupt decrease in [I2] etc. for one to conclude the mechanism to be plausible. The plausible mechanism contains HIO2, HIO, I–, H2I2O3, and H3I3O5 as intermediates and the second-order back-activation step 2HlO2+ HIO + H2O2→ 3HIO2+ H2O as the key step for the oscillation, which results from the sequence of HIO2+ HIO ⇌ H2I2O3, H2I2O3⇌ H3I3O5, and H3I3O5+ H2O2→ 3HIO2+ H2O. The oscillation source of the mechanism has been found to be in conformity with the Brusselator." @default.
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- W2010982989 date "1974-01-01" @default.
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- W2010982989 title "Mechanism of the oscillatory decomposition of hydrogen peroxide in the presence of iodate ion, iodine etc." @default.
- W2010982989 doi "https://doi.org/10.1039/fs9740900055" @default.
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