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- W2010991102 abstract "Kyanite phases Al2SiO5 (I), Al2GeO5 (II) and Cr2GeO5 (III) were synthesized at 20 kb/1000°C (I, II) and at 1 atm/1150°C (III). Powder X-ray patterns for II and III are presented in comparison with that of I. Triclinic lattice constants are a0 = 7.127 (7.253, 7.422), b0 = 7.858 (8.011, 8.244), c0 = 5.570 (5.649, 5.815) Å, α = 89.99 (89.97, 90.58), β = 101.22 (101.23, 101.10), γ = 106.04 (106.05, 106.01)°, and V0 = 293.6 (308.9, 339.9) Å3 for the kyanite phases I (II, III, respectively). Infrared absorption spectra of I (II, III) were measured between 1400 and 200 cm−1. Band shifts produced by the isomorphous substitutions allow tentative band assignments of the Al2SiO5-kyanite spectrum: 1032, 1009, 940 cm−1 ν3 (SiO4); 898 cm−1 ν1 (SiO4); 720, 438 cm−1 ν4, ν2 (SiO4) ?; banes between 674 and 505 cm−1 and at 467 cm−1 are mainly due to octahedral Al–O vibrations." @default.
- W2010991102 created "2016-06-24" @default.
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- W2010991102 date "1975-04-01" @default.
- W2010991102 modified "2023-09-23" @default.
- W2010991102 title "Al<sub>2</sub>SiO<sub>5</sub>, Al<sub>2</sub>GeO<sub>5</sub>and Cr<sub>2</sub>GeO<sub>5</sub>kyanites: X-ray powder data and infrared absorption spectra" @default.
- W2010991102 doi "https://doi.org/10.1107/s0021889875010540" @default.
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