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- W2011010795 abstract "Two methods are presented for the preparation of the α and β anomers of 2,3,4,6-tetra-O-acetyl-5-thio-d-glucopyranosyl azide. These methods are comparable in yield, but the one that converts a glucopyranosyl bromide into the azide is preferable because of easier purification. After chromatographic separation, the α and β anomers were analysed by NMR spectroscopy. The crystal and molecular structure of the β anomer was determined by X-ray diffraction. It crystallises in space group P21 [a=11.729(3), b=7.305(3), c=11.363(3)Å, β=107.63(5)°, Z=2]. The hexopyranose ring of the β anomer assumes a 4C1 conformation and the orientation of the azido group is compatible with the requirements of the exo-anomeric effect. This geometry is compared to that of other similar structures." @default.
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- W2011010795 date "1999-05-01" @default.
- W2011010795 modified "2023-10-18" @default.
- W2011010795 title "Synthesis and structural studies of anomeric 2,3,4,6-tetra-O-acetyl-5-thio-d-glucopyranosyl azides" @default.
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- W2011010795 doi "https://doi.org/10.1016/s0008-6215(99)00097-x" @default.
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