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- W2011014439 abstract "Two families of “push−pull” phthalocyanines 1−3 having an unusually strong dipole moment have been prepared. The syntheses of unsymmetrically substituted phthalocyanines 1a,b and 2 bearing one or two electron-withdrawing 4-nitrophenylethynyl moieties, respectively, and six alkoxy substituents were performed by combination of a zinc or nickel templated cyclotetramerization and cross-coupling palladium mediated methodologies. In a similar way, the “push−pull” compounds 3a,b having a reversal substitution pattern, characterized by the presence of one electron-donor 4-(dimethylamino)phenylethynyl unit and six strong acceptor alkylsulfonyl substituents were prepared. The compounds show very large second-order nonlinear optical responses." @default.
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- W2011014439 date "2010-06-03" @default.
- W2011014439 modified "2023-10-18" @default.
- W2011014439 title "ChemInform Abstract: Synthesis of Novel Push-Pull Unsymmetrically Substituted Alkynyl Phthalocyanines." @default.
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- W2011014439 doi "https://doi.org/10.1002/chin.200033174" @default.
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