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- W2011014893 abstract "He scattering from the clean Pd(100) surface yields extremely weak diffraction beams relative to the specular, corresponding to a very small maximum corrugation amplitude of ~ 0.04 Å. Hydrogen adsorption at a temperature of 110 K leads to the formation of a c(2 × 2) ordered phase at a coverage of 0.5 monolayers and a (1 × 1) phase at saturation coverage. The maximum corrugation amplitude of the c(2 × 2)H is ~0.13 Å; surface charge density calculations using overlapping atomic charge densities indicate a normal distance of the hydrogens to the topmost Pd layer dn ≅ 0.65–0.70 Å corresponding to a H-Pd bonding distance of ~ 2.05 Å in the fourfold hollow sites. The result that the maximum corrugation amplitude of the (1 × 1) hydrogen phase, with ~ 0.025 Å, even smaller than that of the clean surface may indicate a movement of the hydrogens closer to the topmost metal layer, when the coverage is increased from 0.5 monolayers to saturation." @default.
- W2011014893 created "2016-06-24" @default.
- W2011014893 creator A5014397428 @default.
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- W2011014893 date "1984-12-01" @default.
- W2011014893 modified "2023-09-26" @default.
- W2011014893 title "Hydrogen chemisorption on Pd(100) studied with he scattering" @default.
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- W2011014893 doi "https://doi.org/10.1016/0039-6028(84)90038-4" @default.
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