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- W2011015384 abstract "The crystalline compounds M(II)2(ATP)(TPY)2·6H2O (MCu,Zn), prepared from aqueous solution at pH 6, have similar molecular and crystal structure as shown by infrared spectroscopy and X-ray powder diffraction. They contain a fully deprotonated nucleotide molecule (ATP4−) which acts as a ligand through the phosphate chain. The FT-IR analysis shows a red shift of 55 cm−1 for the NH2 group deformation vibration, and a blue shift of 15 cm−1 for stretching vibrations involving the γ-phosphate group upon complexation. The metal cations have a pseudooctahedral coordination geometry with an equatorial N3O donor set. Relevant EPR parameters for Cu2+ doped into the zinc derivative are: g∥, 2.284; A∥, 160.0(5) cm−1." @default.
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- W2011015384 date "1996-02-01" @default.
- W2011015384 modified "2023-09-26" @default.
- W2011015384 title "Synthesis and characterization of crystalline copper(II)- and zinc(II)-adenosine 5′-triphosphate (ATP) -2,2′:6′.2″-terpyridine (TPY) ternary compounds" @default.
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- W2011015384 doi "https://doi.org/10.1016/0162-0134(95)00037-2" @default.
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