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- W2011025008 abstract "Microporous poly(tetrafluoroethylene) (PTFE) and Celgard® films were used as support material for Nafion®-based composite membranes. The microporous supports were impregnated by soaking in a 18 wt% Nafion®/ethanol solution. Although there was considerable Nafion® uptake by Celgard® (43–45 wt%), the conductivity at 65°C of 0.021 S/cm (Celgard® 2400) or 0.027 S/cm (Celgard® 2500) is relatively low in comparison to that of 0.114 S/cm for Nafion® 112. In contrast, a larger uptake (∼70 wt%) and conductivity (0.101 S/cm) were measured for the microporous PTFE support. Because the Nafion®/PTFE composites are only 31 μm thick, their areal resistance is lower than that of Nafion® 112 membranes: 0.031 vs 0.036 Ω cm2. Nafion® is uniformly distributed across the PTFE support, as evidenced by EDAX visualization of Ag+-exchanged membranes, but does not completely plug the micropores, as suggested by the relatively low bubble-point and the relatively high N2 and O2 permeabilities of the composites." @default.
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- W2011025008 date "1998-05-01" @default.
- W2011025008 modified "2023-10-17" @default.
- W2011025008 title "Nafion®-based composite polymer electrolyte membranes" @default.
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- W2011025008 doi "https://doi.org/10.1016/s0013-4686(97)10151-7" @default.
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