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- W2011036773 abstract "The partial vapor pressures of monomeric and dimeric molecules in equilibrium with solid thallium(I) fluoride were measured by simultaneous Knudsen-effusion and torsion-effusion in the temperature range 516 to 572 K. The partial pressures of TlF(g) and Tl2F2(g) are expressed by: ln(pmpo) = A − B(KT). The values of A and B are given. The calculated partial pressures established that the dimer constitutes 43 moles per cent of the equilibrium vapor. The third-law values of the standard molar enthalpies of sublimation ΔsubHmo(298.15 K) are (139.9±5.0) and (148.8±5.0) kJ·mol−1 for TlF(g) and Tl2F2(g), respectively. The third-law standard molar enthalpy change for the dissociation: Tl2F2(g) = 2TlF(g) is ΔrHmo(298.15 K) = (131±5) kJ·mol−1." @default.
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- W2011036773 date "1985-03-01" @default.
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- W2011036773 title "Thermodynamics of the sublimation of thallium(I) fluoride by simultaneous Knudsen-effusion and torsion-effusion" @default.
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- W2011036773 doi "https://doi.org/10.1016/0021-9614(85)90017-5" @default.
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