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- W2011051329 abstract "Metastable anionic states are very useful for describing resonances in electron-molecule scattering processes. However, a rigorous definition of such metastable states does not exist and their numerical representation, in particular in cases of very broad resonances, is difficult. In the present paper, the formalism of the R-matrix theory is employed to develop a general concept for constructing metastable electronic states. The discretization of the scattering continuum by the R-matrix formalism allows us to define metastable anionic states similar to diabatic states in cases of avoided crossings of potential curves in molecules. This present technique also allows the solution of the background scattering problem and the determination of the energy-dependent decay width of resonances. The concept is demonstrated for the state of , the state of and the state of ." @default.
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- W2011051329 date "1998-09-14" @default.
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- W2011051329 title "Characterization of metastable anionic states within theR-matrix approach" @default.
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- W2011051329 doi "https://doi.org/10.1088/0953-4075/31/17/017" @default.
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