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• W2011051811 abstract "A series of phosphino-imidazolium salts (1–4), which are composed of the phosphine-incorporated imidazolium cations and the corresponding counter-anions of PF6−, TfO−, and BF4−, are used in Rh-catalyzed hydroformylation. It was found that when the ionic Rh(III)-complex (1A, [RhIIICl4(L)2]PF6, L = 1-butyl-2-diphenylphosphino-3-methylimidazolium) was used as the pre-catalyst for hydroformylation of 1-octene, its inert catalytic activity could be efficiently tailored by the ion-pair synergetic effect of ligand 1–4 in water suspension. The single crystal structures of 1, 2, and 4 indicate that the hydrogen bonding network is developed between the cation and anion of ion-pairs 1 and 4, but is completely non-inexistent in 2." @default.
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• W2011051811 date "2014-05-01" @default.
• W2011051811 modified "2023-10-16" @default.
• W2011051811 title "Ion-pair effect of phosphino-imidazolium salts on Rh(III)-complex catalyzed hydroformylation of 1-octene in water suspension" @default.
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• W2011051811 doi "https://doi.org/10.1016/j.catcom.2014.02.017" @default.
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