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• W2011053032 abstract "Abstract As an example of cyclic voltammograms associated with heterogeneous electrode kinetics at microcylinder electrodes, reduction waves of Fe 3+ were measured at carbon fiber electrodes. They showed the following three distinctive forms depending on the potential sweep rate: (a) peak-shaped waves as are often observed at a large planar electrode; (b) peak potentials too vague to be determined; (c) a loss of the anodic peak due to convection at very slow potential sweep rates. A graphical method of determining the peak potentials of waves (b) is presented. Peak potentials and half-peak potentials do not depend on the potential sweep rate. This fact is in contrast with the significant dependence on the sweep rate at a large planar electrode. The charge transfer rate constant for Fe 3+ /Fe 2+ was evaluated from the peak potential and the half-peak potential. The value obtained from the peak potential was half of that from the half-peak potential because of heterogeneity of the carbon fiber surface. The rate constant from the peak potential provides a quantitative measure of surface activation of carbon fiber electrodes. Application of this evaluation was directed to carbon fabric electrodes employed in redox flow batteries." @default.
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• W2011053032 date "1988-06-01" @default.
• W2011053032 modified "2023-09-25" @default.
• W2011053032 title "Estimation of charge transfer kinetic parameters from irreversible cyclic voltammograms at carbon fiber electrodes" @default.
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• W2011053032 doi "https://doi.org/10.1016/0022-0728(88)80128-1" @default.
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