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- W2011053958 abstract "Mono deuterio-1,5-dimethylsemibullvalene is studied by the isotopic perturbation method with respect to the equilibrium of the valence isomerization. It emerges that deuterium prefers the cyclopropane position. From the temperature dependence of the splittings in the 13C NMR spectra the ground state enthalpy difference in mono deuterio-1,5-dimethylsemibullvalene is calculated to be 484 J mol−1." @default.
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- W2011053958 date "1982-03-01" @default.
- W2011053958 modified "2023-10-14" @default.
- W2011053958 title "Isotopic perturbation of a degenerate valence isomerization. A13C NMR study of deuterio-1,5-dimethylsemibullvalene" @default.
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- W2011053958 doi "https://doi.org/10.1002/mrc.1270180313" @default.
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