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- W2011058847 abstract "Abstract The role of hydrophobic effects in revered-phase liquid chromatography is examined. The molecular weight or structural selectivity resulting from hydrophobic effects relative to dispersion forces is discussed, and it is shown that in general a selectivity up to twice as great is possible in the former case. Hydrophobic selectivity can be accounted for using a new topological index, the molecular connectivity, to represent solute surface area. Selectivity as a function of organic modifier type and composition is explored. By simultaneously varying both of the above parameters such that retention is normalized, it is shown that hydrophobic selectivity is approximately independent of organic modifiers. Some differences in separation as a function of organic solvent are, however, observed when mixtures containing solutes of different functional groups are employed. Finally, hydrophobic selectivity is roughly constant under time normalization conditions based on temperature-organic phase composition changes." @default.
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- W2011058847 title "Hydrophobic effects in reversed-phase liquid chromatography" @default.
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- W2011058847 doi "https://doi.org/10.1016/s0021-9673(00)84032-7" @default.
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