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- W2011083134 abstract "The simultaneous determination of log K° and ΔH° for anion–cation interactions is examined with reference to the reactions M3++ SO42–⇌ MSO4+ and MSO4++ SO42–⇌ M(SO4)2–(M = lanthanoid). Limitations of the ‘entropy titration’ approach are outlined. From published enthalpimetric data ΔH° values for the formation of the monosulphate ion pairs have been recalculated using published K° data. For the formation of the bis(sulphate) ion pair ΔH° and K° have been recalculated from enthalpimetric data by graphical methods and by general non-linear least-squares analysis." @default.
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- W2011083134 date "1974-01-01" @default.
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- W2011083134 title "Entropy titrations: a reassessment of data for the reaction of the sulphate ion with trivalent lanthanoid ions" @default.
- W2011083134 doi "https://doi.org/10.1039/dt9740001108" @default.
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