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- W2011085132 abstract "A novel method for the highly sensitive determination of perchlorate was proposed. It was based on solvent extraction in the presence of Ru(bpy)2+3 followed by Ru(bpy)2+3 electrochemiluminescent determination. A linear calibration was obtained over the range of 0.1 to 10 μmol l−1 with a correlation coefficient of 0.998. The detection limit (S/N=3) was 5.0×10−8 mol l−1. The relative standard deviation for 10 replicates of 1 μmol l−1 perchlorate was 1.6%. Interference studies suggest that this method is selective for the determination of perchlorate. Application of this method to the highly sensitive determination of other anions is suggested." @default.
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- W2011085132 date "1999-10-01" @default.
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- W2011085132 title "Electrochemiluminescent determination of perchlorate by solvent extraction in the presence of Ru(bpy) 2+3" @default.
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- W2011085132 doi "https://doi.org/10.1016/s1388-2481(99)00089-2" @default.
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