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- W2011097181 abstract "Abstract Monomeric Ir(CO) 2 acac as it occurs in dilute solutions ( −3 M) absorbs only in the UV spectral region and shows a greenish luminescence ( λ max = 480 nm) which originates from the lowest-energy intraligand (acac) triplet. At higher concentrations a yellow coloration is observed which is attributed to the formation of oligomers. At 77 K these solutions turn blue owing to the presence of oligomers which are characterized by strong metal–metal interactions. These blue oligomers display an intense red luminescence which consists of a fluorescence at λ max = 662 nm and a phosphorescence at λ max = 815 nm." @default.
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- W2011097181 date "2005-01-01" @default.
- W2011097181 modified "2023-10-12" @default.
- W2011097181 title "Excited state properties of (acetylacetonato)dicarbonyliridium(I)" @default.
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- W2011097181 doi "https://doi.org/10.1016/j.inoche.2004.08.026" @default.
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