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• W2011102842 abstract "The adsorption and thermal reactions of an alkyl nitrite, t-C4H9ONO, on Pt(111) are reported. Dissociative chemisorption at the weak (171 kJ/mol) RONO bond accompanies adsorption at 115 K, forming adsorbed t-C4H9O and NO. During heating to 200 K, some t-C4H9O dehydrogenates at the γ-carbon (methyl group) to form a proposed oxametallacycle species that dehydrogenates further upon heating to 250 K. tert-Butyl alcohol, t-C4H9OH, desorbs in three coverage-dependent peaks (200, 250, and 300 K) attributable to hydrogenation of both t-C4H9O and the oxametallacycle. The yields and reaction paths depend on the initial dose of t-C4H9ONO. Vibrational modes of the oxametallacycle were compared for several plausible structures, with modes calculated using density functional theory. Among these structures, a four-membered oxametallacycle ring (containing only one Pt atom in the ring) gave the best agreement with the experimental data. Finally, a reaction path potential energy diagram was constructed." @default.
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• W2011102842 date "2000-12-29" @default.
• W2011102842 modified "2023-10-17" @default.
• W2011102842 title "Thermal Activation of <i>tert</i>-Butyl Nitrite on Pt(111): <i>tert</i>-Butoxy Dehydrogenation and Oxametallacycle Formation" @default.
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• W2011102842 doi "https://doi.org/10.1021/la001315v" @default.
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