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- W2011121328 abstract "The asymmetric hydroformylation of 2- and 3-vinylfurans (2a and 2b, resp.) was investigated by using [Rh{(R,S)-binaphos}] complexes as catalysts ((R,S)-binaphos = (11bS)-4-{[1R)-2′-phosphino[1,1′-binaphthalen]-2-yl]oxy}dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin; 1). Hydroformylation of 2 gave isoaldehydes 3 in high regio- and enantioselectivities (Scheme 2 and Table). Reduction of the aldehydes 3 with NaBH4 successfully afforded the corresponding alcohols 5 without loss of enantiomeric purity (Scheme 3)." @default.
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- W2011121328 date "2006-08-01" @default.
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- W2011121328 title "Asymmetric Hydroformylation of Vinylfurans Catalyzed by {(11bS)-4-{[(1R)-2′-Phosphino[1,1′-binaphthalen]-2-yl]oxy}dinaphtho[2,1-d:1′,2′-f]- [1,3,2]dioxaphosphepin}rhodium(I) [RhI{(R,S)-binaphos}] Derivatives" @default.
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- W2011121328 doi "https://doi.org/10.1002/hlca.200690166" @default.
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