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- W2011161208 abstract "Abstract The phase diagram of binary system of 4-n-pentyl 4′cyanobiphenyl (component 1) and 4-n pentylphenyl 4-n′hexyloxy benzoate (component 2) is presented, which shows the presence of an injected smetic phase. Refractive indices and densities for ten different compositions of this mixture and for one pure component are measured. The molecular polarizabilities are calculated from refractive indices using Vuks' method. The orientational order parameters are determined from the polarizability values. Experimental order parameters are compared with McMillan's theory for mixtures having injected smectic phase, and with Maier-Saupe theory for others having a nematic phase only. Mixtures having almost equal molar concentrations are less orientationaly ordered compared to others. The change in physical parameters is continuous for mixtures withx > 0.5, whereas there is an abrupt change of the values of the parameters in going from smectic to nematic phase for mixtures having × <0.5, × being the mole fraction of component 1. For most of the mixtures two-phase coexistence region for both N/S and N/I transitions are observed. Key Words: Binary mixtureinjected smectic phaserefractive indicesdensitiesorder parameters" @default.
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- W2011161208 title "Optical birefringence, density and order parameter of an ester-biphenyl mixture exhibiting an injected smectic phase" @default.
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- W2011161208 doi "https://doi.org/10.1080/01411599408200323" @default.
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