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- W2011176713 abstract "Ionisation potentials are derived for the neon-like ions of Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge, As, Se, and Y by applying the Ritz law to observed wavelengths in one or both of the 2p6 1So-2p5nd 1P1, 3D1 Rydberg series. The wavelengths are adjusted to allow for mutual and configuration interaction. The potential of neon-like Ar IX is determined from energy levels in the 2p5nd 3F4 series. The derived potentials systematically exceed the predictions of Edlen's (1971) non-relativistic semi-empirical formula. The differences are much larger than experimental uncertainties and are interpreted as a relativistic contribution to the ionisation potential. The Edlen formula is amended to allow for the newly derived potentials and to include theoretical calculations of the relativistic contribution by Snyder. The revised formula reproduces the potentials for Si V and higher ions to within experimental uncertainty. Discrepancies for Ne I to Al IV may be due to the correlation energy." @default.
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- W2011176713 date "1980-01-01" @default.
- W2011176713 modified "2023-09-25" @default.
- W2011176713 title "Ionisation Potentials in the Neon-Like Isoelectronic Sequence" @default.
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- W2011176713 doi "https://doi.org/10.1088/0031-8949/21/1/013" @default.
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