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- W2011183492 abstract "The Claisen rearrangement of allyl aryl ethers provides a convenient route to obtain allyl phenols which are precursors to a variety of natural products. All uncatalyzed Claisen rearrangements are energy intensive requiring temperatures above 200 °C whereas those using homogeneous acid catalysts leads to a loss in yield and selectivity, in addition to pollution problems. In the current work, the Claisen rearrangement of allyl-4-methoxyphenyl ether to 2-allyl-4-methoxyphenol was investigated at 90 °C using chlorobenzene as a solvent over several solid acid catalysts such as dodecatungstophosphoric acid/hexagonal mesoporous silica (HMS), Cs2.5H0.5PW12O40/K10 clay, sulfated zirconia and a new mesoporous solid superacid UDCaT-5. 2-Allyl-4-methoxyphenol is used in perfumes, flavors, soaps, detergents, air fresheners, and cosmetic materials. UDCaT-5 was found to be superior, robust and recyclable and 100% selective. A complete theoretical and experimental analysis is also presented. This is a 100% atom economical and efficient process." @default.
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- W2011183492 date "2005-09-01" @default.
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- W2011183492 title "Claisen rearrangement with a novel solid superacid UDCaT-5: Atom economical and selective conversion of allyl-4-methoxyphenyl ether into 2-allyl-4-methoxyphenol" @default.
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- W2011183492 doi "https://doi.org/10.1016/j.micromeso.2005.05.002" @default.
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